Ion mobility: Difference between revisions

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<div class="definition"><div class="short_definition">(<br/>''Or'' ionic mobility.) In gaseous electric [[conduction]], the [[average velocity]] with which  a given [[ion]] drifts through a specified gas under the influence of an [[electric field]] of unit strength.</div><br/> <div class="paragraph">Mobilities are commonly expressed in units of meters per second per volt per meter [m s<sup>&minus;1</sup>(V  m<sup>&minus;1</sup>)<sup>&minus;1</sup>]. In a vacuum, a single gaseous ion subjected to any nonzero [[potential gradient]] would  accelerate indefinitely; but in the midst of a gas the ion continually experiences collisions with gas  molecules. These encounters tend to break up its [[trajectory]] into a series of short intervals of  [[acceleration]] punctuated by deflections. The net result is that the ion's gross motion resembles  [[drift]] at a uniform [[velocity]]. The [[mobility]] depends not only upon the nature of the ion and gas  but also upon the [[density]] of the gas, for the latter controls the [[mean free path]] of the ion. In  [[atmospheric electricity]], the mobilities of small and large ions weight their relative importance  in atmospheric [[conduction]]. Small ions have mobilities of about 1.3 &times; 10<sup>&minus;4</sup> m s<sup>&minus;1</sup>(V m<sup>&minus;1</sup>)<sup>&minus;1</sup> in air  at [[sea level]] with negative small ions exhibiting slightly greater values than do the positive small  ions. High humidities suppress [[small ion]] mobilities slightly. [[Large ions]] have mobilities of only  about 4 &times; 10<sup>&minus;7</sup> m s<sup>&minus;1</sup> (V m<sup>&minus;1</sup>)<sup>&minus;1</sup> at sea level, their sluggishness being due to their great mass.</div><br/> </div><div class="reference">Wait, C. R., and W. D. Parkinson 1951. Compendium of Meteorology. 124&ndash;125. </div><br/> <div class="reference">Isra&euml;l, H. 1951. Compendium of Meteorology. 146&ndash;147. </div><br/>  
<div class="definition"><div class="short_definition">(''Or'' ionic mobility.) In gaseous electric [[conduction]], the [[average velocity]] with which  a given [[ion]] drifts through a specified gas under the influence of an [[electric field]] of unit strength.</div><br/> <div class="paragraph">Mobilities are commonly expressed in units of meters per second per volt per meter [m s<sup>-1</sup>(V  m<sup>-1</sup>)<sup>-1</sup>]. In a vacuum, a single gaseous ion subjected to any nonzero [[potential gradient]] would  accelerate indefinitely; but in the midst of a gas the ion continually experiences collisions with gas  molecules. These encounters tend to break up its [[trajectory]] into a series of short intervals of  [[acceleration]] punctuated by deflections. The net result is that the ion's gross motion resembles  [[drift]] at a uniform [[velocity]]. The [[mobility]] depends not only upon the nature of the ion and gas  but also upon the [[density]] of the gas, for the latter controls the [[mean free path]] of the ion. In  [[atmospheric electricity]], the mobilities of small and large ions weight their relative importance  in atmospheric [[conduction]]. Small ions have mobilities of about 1.3 &times; 10<sup>-4</sup> m s<sup>-1</sup>(V m<sup>-1</sup>)<sup>-1</sup> in air  at [[sea level]] with negative small ions exhibiting slightly greater values than do the positive small  ions. High humidities suppress [[small ion]] mobilities slightly. [[Large ions]] have mobilities of only  about 4 &times; 10<sup>-7</sup> m s<sup>-1</sup> (V m<sup>-1</sup>)<sup>-1</sup> at sea level, their sluggishness being due to their great mass.</div><br/> </div><div class="reference">Wait, C. R., and W. D. Parkinson 1951. Compendium of Meteorology. 124&ndash;125. </div><br/> <div class="reference">Isra&#x000eb;l, H. 1951. Compendium of Meteorology. 146&ndash;147. </div><br/>  
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Latest revision as of 14:29, 20 February 2012



ion mobility

(Or ionic mobility.) In gaseous electric conduction, the average velocity with which a given ion drifts through a specified gas under the influence of an electric field of unit strength.

Mobilities are commonly expressed in units of meters per second per volt per meter [m s-1(V m-1)-1]. In a vacuum, a single gaseous ion subjected to any nonzero potential gradient would accelerate indefinitely; but in the midst of a gas the ion continually experiences collisions with gas molecules. These encounters tend to break up its trajectory into a series of short intervals of acceleration punctuated by deflections. The net result is that the ion's gross motion resembles drift at a uniform velocity. The mobility depends not only upon the nature of the ion and gas but also upon the density of the gas, for the latter controls the mean free path of the ion. In atmospheric electricity, the mobilities of small and large ions weight their relative importance in atmospheric conduction. Small ions have mobilities of about 1.3 × 10-4 m s-1(V m-1)-1 in air at sea level with negative small ions exhibiting slightly greater values than do the positive small ions. High humidities suppress small ion mobilities slightly. Large ions have mobilities of only about 4 × 10-7 m s-1 (V m-1)-1 at sea level, their sluggishness being due to their great mass.

Wait, C. R., and W. D. Parkinson 1951. Compendium of Meteorology. 124–125.

Israël, H. 1951. Compendium of Meteorology. 146–147.


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